反应条件对水热合成二硫化镍NiS_2粉晶的影响Influence of the Reaction Condition on Synthesizing NiS_2 Powder by Hydrothermal Technique
蒋莉;郑毓峰;孙言飞;陈艳华;张玲;
摘要(Abstract)：
本文采用水热法一步合成了二硫化镍粉晶,利用X射线衍射(XRD),扫描电子显微镜讨论了样品N iS2粉晶的晶体结构及形貌,研究了X射线衍射峰积分强度以及半峰宽等随反应条件的变化,并分析了N iS2粉晶的合成机理.
关键词(KeyWords)： 二硫化镍(NiS_2);水热法;XRD
基金项目(Foundation):
作者(Authors): 蒋莉;郑毓峰;孙言飞;陈艳华;张玲;
参考文献(References)：
- [1]Ennaou i A,T ribu tsch H.Iron su lph ide so lar ce lls[J].So l C e ll,1984,13(2):199-200.
- [2]Bonneau P R,Sh ibao R K,K aner R B.Low-T em perature P recursor Syn thes is of C rysta lline N icke lD isu lfide[J].InorgChem,1990,29:2511-2514.
- [3]G rau J,A k inc M.Syn thes is of n icke l su lfide by hom ogeneous prec ip itation from ac id ic so lu tions of th ioacetam ide[J].Journa l of the Am erican C eram ic Soc iety,1996,79(4):1073-1082.
- [4]O livas A,C ruz-R eyes J,A va los M.In fluence of preparation cond itions on form ation of crysta lline phases of n icke lsu lfide[J].M ateria ls L etters,1999,38:141-144.
- [5]CHEN X iaohu i,FAN R ong.Low-T em perature Hydrotherm a l Syn thes is of T rans ition M eta l D icha lcogen ides[J].ChemM ater,2001,13:802-805.
- [6]Q IAN X uefeng,L I Y adong,X IE Y i,et a l.T he syn thes is and m orpho log ica l con tro l of nanocrysta lline pyrite n icke ld isu lfide and coba lt d isu lfide[J].M ater Chem Phys,2000,66:97-99.
- [7]ZHANG X inm ing,Q IAN X uefeng,W ang Cheng,et a l.So lven t-therm a l preparation of nanocrysta lline pyrite n icke ld isu lph ide[J].M ater Sc i Eng,1999,B 57:170.
- [8]耿新玲,袁伟.液相法制备N i3S4纳米粉[J].无机材料学报,2003,18(1):149-155.
- [9]增德文,李作刚,谭鹏夫,等.硫化沉镍条件的热力学分析[J].中国有色金属学报,1996,6(3):35-38.