焦煤热溶萃取收率与其特性参数的相关性研究(英文)Characterization of Coking Coals Using Solvent Extraction at 350 ℃
程小爱,坚一明,Inamullah Mian,钟梅,刘景梅
摘要(Abstract):
工业分析和元素分析等传统的煤的基本分析很难与焦煤的特征参数(如最大流动度和最大膨胀度等)建立很好的相关性.所以,本文提出一种新型的煤的热溶萃取法,通过萃取物的收率及性质来预测焦煤的基本特征参数.选取了11种强粘结性和弱粘结性煤,采用热溶萃取法将其分为三种主要组分:低分子量萃取物、高分子量萃取物、萃取残渣.结果表明,不同煤种的三组分收率相差较大,但是不同煤中获得的同一组分性质非常相似.通过对原煤及其各萃取产物的工业分析、元素分析、热解特性分析、热塑性分析及分子量分布分析等详细表征,对两者的性质建立较深入的理解.然后通过数学模拟,获得了三组分收率与焦煤基本特征参数(最大流动度和最大膨胀度)的相关性方程,相关系数分别达到0.79和0.94.可见,焦煤的热溶萃取产物收率与其特征参数有较好的相关性.所以,本文提出的热溶萃取法来预测焦煤的基本特征参数是可行的.
关键词(KeyWords): 热溶萃取;焦煤;最大流动度;最大膨胀度
基金项目(Foundation): Project supported by the National Natural Science Foundation of China(21776109,U1510119)
作者(Author): 程小爱,坚一明,Inamullah Mian,钟梅,刘景梅
DOI: 10.13568/j.cnki.651094.2018.04.006
参考文献(References):
- [1]Tao M A,Zhang Y X.Numerical Simulation and Analysis on the Distribution of Characteristic Parameters Inside the Methanation Fixed Bed Reactor Based on Ansys-CFX[J].Journal of Xinjiang University,2015,32(2):140-145.
- [2]Cui H Y,MA FengYun,Liu J C,et al.Influence of Steelmaking Flue Dust as a Catalyst of the Direct Liquefaction Performance of Coal from Jiangjunmiao,Xinjiang at Low Pressure[J].Journal of Xinjiang University,2011,28(4):383-388.
- [3]Varma A K.Thermogravimetric investigations in prediction of coking behaviour and coke properties derived from inertinite rich coals[J].Fuel,2002,81(10):1321-1334.
- [4]Hiroyuki S,Osamu I,Masashi I,et al.Fluidity of coal residues after extraction with mixed solvents[J].Fuel,1989,68(8):978-982.
- [5]Wachowska H,Kozlowski M.The influence of extraction with organic solvents on coking properties of raw and reduced coals[J].Fuel&Energy Abstracts,1996,37(3):517-521.
- [6]Grint A,Mehani S,Trewhella M,et al.Role and composition of the mobile phase in coal[J].Fuel,1985,64(10):1355-1361.
- [7]Takanohashi T,Takahiro Yoshida A,Iino M,et al.Effect of Heavy Solvent-Soluble Constituents on Coal Fluidity[J].Energy&Fuels,1998,12(5):913-917.
- [8]Ouchi K,Tanimoto K,Makabe M,et al.Relation between fluidity and solvent extraction yield of coals[J].Fuel,1983,62(10):1227-1229.
- [9]Kouichi M,Makoto S,Kazuhiro M,et al.Extraction of coal at 300℃ to 350℃ to produce precursors for chemicals[Z].pittsburgh:the 15th annual international pittsburgh coal conference,1998:14-18.
- [10]Kouichi M,Makoto S,Kazuhiro M,et al.Extraction of coal below 350℃ in flowing non-polar solvent[J].Fuel,2001,80(11):1573-1582.
- [11]Ryuichi A,Kyosuke N,Masayuki O,et al.Fractionation of coal by use of high temperature solvent extraction technique and characterization of the fractions[J].Fuel,2008,87(4-5):576-582.
- [12]Takanohashi T,Takahiro Yoshida A,Iino M,et al.Production of clean fuels by solvent skimming of coal at around 350℃[J].Fuel,2004,83(6):733-738.
- [13]Graham H,Lawson G J.Extraction of intermediate and low rank coals with HA0 Philip Cahill[J].Fuel,1988,67:7.
- [14]Garcia R.Supercritical gas extracts from low-quality coals:on the search of new precursors for carbon materials[J].Fuel Processing Technology,2004,86(2):205-222.
- [15]Fong W S.Plastic behaviour of coal under rapid-heating high-temperature conditions[J].Fuel,1986,65(2):195-201.
- [16]Ignasiak B S,Nandi B N,et al.Oxidation studies on coking coal related to weathering:(1)Chromatographic analysis of pyrolysis gases as a method for studying coal weathering[J].Fuel,1970,49(2):214-221.
- [17]Ignasiak B S,Clugston D M,Montgomery D S.Oxidation studies on coking coal related to weathering:Part 2.The distribution of absorbed oxygen in the products resulting from the pyrolysis of slightly oxidized coking coal[J].Fuel,1972,51(1):76-80.
- [18]Ignasiak B S,Szladow A J,Montgomery D S.Oxidation studies on coking coal related to weathering.3.The influence of acidic hydroxyl groups,created during oxidation,on the plasticity and dilatation of the weathered coking coal[J].Fuel,1974,53(1):12-15.
- [19]Wachowska H M,Nandi B N,Montgomery D S.Oxidation studies on coking coal related to weathering 4.Oxygen linkages influencing the dilatometric properties and the effect of cleavage of ether linkages[J].Fuel,1974,53(3):212-219.
- [20]Boyer A F.Controlled oxidation of coal[C].London:in Proceedings of the International Conference on Chemical Engineering in the Coal Industry,1956:24.
- [21]Lowry H H.Chemistry of coal utilization:supplementary volume[M].New York:John Wiley&Sons Inc,1963.