配合物[Cu(mpa)L]·H_2O的水热合成与表征Synthesis and Characterization of a New Complex:[Cu(mpa)L]·H_2O
李辉,刘婷婷,赵本桉,刘罡,王吉德,岳凡
摘要(Abstract):
采用水热法合成了一种新的配合物[Cu(mpa)L]_2·H_2O(mpa=间苯二甲酸,L=4′-(4-甲氧基苯基)-2,2′:6′2″-三联吡啶),并通过红外光谱、元素分析和热重分析对该配合物进行了表征,采取X射线单晶衍射测定了其结构.该配合物属于单斜晶系,P2_1/c空间群,晶胞参数:a=22.803(5),b=9.608(2),c=27.436(1),β=121.88(2)°,最终偏离因子R1=0.108 2,wR_2=0.245 2.
关键词(KeyWords): 三联吡啶;水热合成;晶体结构
基金项目(Foundation): 高校自然科学基金项目资助(07550033)
作者(Author): 李辉,刘婷婷,赵本桉,刘罡,王吉德,岳凡
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