新疆葵花籽油化学成分分析及抗氧化活性测定Chemical Compositions and Antioxidant Activities of Xinjiang Sunflower Seed Oil
成文虎,马玉花,曹艳红,黄冬群,封顺
摘要(Abstract):
葵花籽是是重要的高产油料作物,葵花籽籽油是一种优质的食用油.本文通过气相色谱–质谱分析手段对葵花籽油进行了全组分分析,鉴定出71种化合物,主要为脂肪酸(44.07%)和醇类化合物(44.38%).并采用邻二氮菲法和DPPH法对其抗氧化性能进行了研究.结果表明:葵花籽油清除羟基自由基能力(EC50=30.36±0.20μg/mL)大于2,6二叔丁基4甲基苯酚(BHT)(EC50=436.70±0.02),但清除DPPH自由基(IC50=4.16±0.10 mg/mL)却小于BHT(IC50=0.069±0.002 mg/mL),实验结果表明葵花籽油具有较强的抗氧化活性,且有很好的食品应用价值.
关键词(KeyWords): 葵花籽油;成分分析;邻二氮菲法;DPPH;抗氧化活性
基金项目(Foundation): 新疆维吾尔自治区科技支疆项目(201191170)资助
作者(Author): 成文虎,马玉花,曹艳红,黄冬群,封顺
参考文献(References):
- [1]郭炎强.水代法生产葵花籽香油的研究[J].郑州工程学院学报,2003,1(3):77-79.
- [2]马宏.新疆主要葵花籽品种脂肪酸组成分析[J].粮油食品科技,2011,5(2):50-51.
- [3]姜波,关紫烽,范圣第,等.葵花籽油脂肪酸含量的气相色谱分析[J].大连民族学院学报,2004,5(2):35-36.
- [4]徐金瑞,邓翌凤,列丽坤.几种抗氧化剂协同作用对葵花籽油稳定性的影响[J].中国油脂,2009,8(3):40-42.
- [5]张坤,朱凤岗,柳仁民.葵花籽油的超临界CO2流体萃取及其GC/MS分析研究[J].山东农业大学学报,2005,36(4):512-516.
- [6]居来提.买苏木.几种食用植物油的营养特点[J].新疆技术监督,2001,1(1):38-38.
- [7]周晓丹,王妍,刘晶.等.橄榄油,葵花籽油和米糠油的氧化稳定性[J].食品科学,2011,32(13):119-121.
- [8]迟晓星,赵东星.水酶法提取葵花籽油的研究[J].中国粮油学报,2010,25(2):71-74.
- [9]李丹华,朱圣陶.GC/MS气相色谱法测定常见植物油中脂肪酸[J].粮食与油脂,2006,(8):46-48.
- [10]Murat T,Mehmet D,徐廷丽.葵花籽油在不同精炼阶段中反式脂肪酸的研究[J].中国油脂,2007,32(2):44-47.
- [11]Georgogianni G,Kontominas G,Pomonis J,et al.Conventional and in situ transesterification of sunflower seed oil for theproduction of biodiesel[J].Fuel Processing Technology,2008,89(5):503-509.
- [12]Bensmira M,Jiang B,Nsabimana C,et al.Effect of Lavender and Thyme incorporation in sunflower seed oil on its resistanceto frying temperatures[J].Food Research International,2007,40(3):341-346.
- [13]徐金瑞,邓翌凤,列丽坤.几种抗氧化剂协同作用对葵花籽油稳定性的影响[J].中国油脂,2009,34(18):40-42.
- [14]凌庆枝,黄秀彦,高莉莉.菜籽油脚衍生气相色谱质谱分析研究[J].油脂工程,2008,6:61-63.
- [15]Bubonja-Sonje M,Giacometti J,Abram M.Antioxidant and antilisterial activity of olive oil,cocoa and rosemary extractpolyphenols[J].Food Chemistry,2011,127(4):1821-1827.
- [16]Cioff G,Pesca S,De Caprariis P,et al.Phenolic compounds in olive oil and olive pomace from Cilento(Campania,Italy)andtheir antioxidant activity[J].Food Chemistry,2010,121(1):105-111.
- [17]Bail S,Stuebiger G,Krist S,et al.Characterisation of various grape seed oils by volatile compounds,triacylglycerol compo-sition,total phenols and antioxidant capacity[J].Food Chemistry,2008,108(3):1122-1132.
- [18]唐文婷,蒲传奋.葵花籽油的氧化稳定性研究[J].粮油食品科技,2011,6(19):19-22.
- [19]刘锡建,王艳辉,马润宇.沙棘果渣中总黄酮提取和精制工艺的研究[J].食品科学,2004,25(6):138-141.
- [20]贾红丽,张丕鸿,计巧灵,等.新疆阿勒泰百里香挥发油化学成分GC-MS[J].食品科学,2009,30(4):224-229.
- [21]Salleh M,Ahmad F,Yen K,et al.Chemical Compositions,Antioxidant and Antimicrobial Activities of Essential Oils of Pipercaninum Blume[J].International Journal of Molecular Sciences,2011,12(11):7720-31.
- [22]Chan K,Ismail M.Supercritical carbon dioxide fluid extraction of Hibiscus cannabinus L.seed oil:A potential solvent-freeand high antioxidative edible oil[J].Food Chemistry,2009,114(3):970-975.
- [23]Joubert E,Winterton P,Britz T,et al.Superoxide anion andα,α-diphenyl-β-picrylhydrazyl radical scavenging capacity ofrooibos(Aspalathus linearis)aqueous extracts,crude phenolic fractions,tannin and flavonoids[J].Food Research Interna-tional,2004,37(2):133-138.
- [24]王媛,王定颖,岳田利.超声波提取葡萄籽油的工艺优化及其抗氧化性研究[J].食品科学,2012,33(10):136-140.