石芳,陈振海,夏熙

摘要(Abstract)：

<正> 二氧化锰作为Leclanche电池的阴极材料由来已久,近年来,又广泛地用作其它电池(如Li-MnO_2、Mg-MnO_2、Al-MnO_2…)的阴极材料,引起电池界广泛的兴趣,对其研究倾注了巨大的努力。研究的方向一是对其阴极机理的研究,一是对各种二氧化锰晶体结构的研究,而其中心即是对二氧化锰电极平衡电位与还原度关系的研究。早期Divers鉴定出电极反应产物的积聚物为MnOOH.MacInnes与Keller发现电池电动势变化值大于由于pH或Zn离子浓度变化引起的变化值。W.Feitkencht及其合作者制备了一系列锰的氧化物,发现二氧化锰与其低价氧化物形成固体溶液的假设与实验观

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作者(Author): 石芳,陈振海,夏熙

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• 62 石芳、陈振海、夏熙,二氧化锰电极研究(Ⅱ),待发表。