1,10-邻菲罗啉并咪唑类受体与阴离子作用研究Synthesis and Recognition Properties of Anion Receptor of 1 H-imidazo[4,5-f][1,10]Phenanthroline Derivatives
张仲良,韩萍,陈华梅,岳凡,孙都成
摘要(Abstract)：
设计并合成了邻菲罗啉并咪唑类阴离子受体2-(4-溴苯酚基)-1H-咪唑[4,5-f][1,10]邻菲罗啉,对其进行了紫外-可见,X衍射单晶衍射表征.通过荧光滴定、理论计算和晶体结构分析,研究了受体对5种阴离子(F、Cl、Br、I、H2PO24、CH3COO)的传感作用及作用机理.结果表明受体对CH3COO、F、H2PO24有很强的传感作用,形成1:1的氢键超分子,对Cl的作用较弱,对Br、I没有明显传感作用.
关键词(KeyWords)： 邻菲罗啉并咪唑衍生物;阴离子识别;晶体结构;理论计算
基金项目(Foundation): 新疆维吾尔自治区自然科学基金(2011211B06)资助
作者(Author): 张仲良,韩萍,陈华梅,岳凡,孙都成
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