金属玻璃中的β-弛豫The β-relaxation in Metallic Glasses
张通,王拓,李强,黎明灿,马旭
摘要(Abstract):
弛豫也称为Johari-Goldstein弛豫,是过冷液体和金属玻璃的固有特征,在过去的几十年一直是材料领域的研究热点.金属玻璃中许多关键本质问题都和弛豫行为(特别是β-弛豫)相关联,因此研究金属玻璃的β-弛豫行为对理解金属玻璃的玻璃化转变现象、机械性能、扩散、物理老化的机制、以及金属玻璃的稳定性都有着很重要的意义.本文简要介绍了金属玻璃β-弛豫的相关研究内容,包括β-弛豫的测试和特征,合金成分对其的影响,以及金属玻璃的塑性与其β-弛豫行为的关联,最后对金属玻璃β-弛豫的研究进行了总结和展望.
关键词(KeyWords): 金属玻璃;β-弛豫;玻璃转变;非晶性能
基金项目(Foundation): 国家自然科学基金(No.51561028,51771161)
作者(Author): 张通,王拓,李强,黎明灿,马旭
DOI: 10.13568/j.cnki.651094.2019.03.008
参考文献(References):
- [1]GREER L A.Metallic glasses…on the threshold[J].Materials Today,2009,12(1-2):14-22.
- [2]WANG W H.Bulk metallic glasses with functional physical properties[J].Advanced Materials,2009,21(45):4524-4544.
- [3]SCHUH C,HUFNAGEL T,Ramamurty U.Mechanical behavior of amorphous alloys[J].Acta Materialia,2007,55(12):4067-4109.
- [4]ASHBY M,GREER A.Metallic glasses as structural materials[J].Scripta Materialia,2006,54(3):321-326.
- [5]JEPPE C,DYRE.Colloquium:the glass transition and elastic models of glass-forming liquids[J].Reviews of Modern Physics,2006,78:953-792.
- [6]LUNKENHEIMER P,WEHN R,LOIDL A.Dielectric spectroscopy on aging glasses[J].Journal of Non-Crystalline Solids,2006,352(42-49):4941-4945.
- [7]WANG W H.The elastic properties,elastic models and elastic perspectives of metallic glasses[J].Progress in Materials Science,2012,57(3):487-656.
- [8]YU H B,WANG W H,BAI H Y,et al.Relating activation of shear transformation zones toβrelaxations in metallic glasses[J].Physical Rewiew B,2010,81:220221.
- [9]WANG Q,LIU J J,YE Y F,et al.Universal secondary relaxation and unusual brittle-to-ductile transition in metallic glasses[J].Materials Today,2017,20(6):293-300.
- [10]YU H B,WANG W H,SAMWER K.Theβrelaxation in metallic glasses:an overview[J].Materials Today,2013,16:183-191.
- [11]WANG L M,CHEN Z M,ZHAO Y,et al.Non-exponentiality of structural relaxations in glass forming metallic liquids[J].Journal of Alloys and Compounds,2010,504:201-204.
- [12]YU H B,WANG Z,WANG W H,et al,Relation betweenβ-relaxation and fragility in lace-based metallic glasses[J].Journal of Non-Crystalline Solids,2012,358(4):869-871.
- [13]YU H B,SHEN X,WANG Z,et al.Tensile plasticity in metallic glasses with pronouncedβrelaxations[J].Physical Review Letters,2012,108:015504.
- [14]YU H B,SAMWER K,WU Y,et al.Correlation between beta relaxation and self-diffusion of the smallest constituting atoms in metallic glasses[J].Physical Review Letters,2012,109(9):095508.
- [15]WANG Z,YU H B,WEN P,et al.Pronounced slowβ-relaxation in la-based bulk metallic glasses[J].Journal of Physics:Condensed Matter,2011,23(14):142202.
- [16]ZHANG C H,HU L N,YUE Y Z,et al.Fragile-to-strong transition in metallic glass-forming liquids[J].Journal of Chemical Physics,2010,133:2627.
- [17]ASHTEKAR S,SCOTT G,LYDING J,et al.Direct imaging of two-state dynamics on the amorphous silicon surface[J].Physical Review Letters,2011,106:235501.
- [18]YU H B,BAI H Y,SAMWER K.Theβ-relaxation in metallic glasses[J].National Science Review,2014,1(3):429-461.
- [19]QIAO J C,CHEN Y H,CASALINI R,et al.Mainα-relaxation and slowβ-relaxation processes in a La30Ce30AL15CO25metallic glass[J].Journal of Materials Science&Technology,2019,35(6):982-986.
- [20]ZHAO Z F,WEN P,SHEN C H,et al.Measurements of slowβ-relaxations in metallic glasses and super cooled liquids[J].Physical Review B,2007,75:17420.
- [21]WANG Z,WEN P,HUO L S.Signature of viscousflow unitsin apparentelasticregime of metallic glasses[J].Appl Phys Lett,2012,101(12):121906.
- [22]WANG Q,PELLETIER J M,DONG Y D,et al.Structural relaxation and crystal lisation of bulk metallic glasses Zr41Ti14Cu12.5Ni10-xBe22.5Fex(x=0 or 2)studied by mechanical spectroscopy[J].Materials Science and Engineering:A,2004,370(1-2):316-320.
- [23]HABASAKI J,NGAI K L.Molecular dynamics simulation of ion dynamic singl assyionic conductors:evidence of the primitive ion hopping process[J].Journal of Non-Crystal line Solids,2006,352(42-49):5170-5177.
- [24]JAMIL A,FAHEEM H,RIAZUDDIN.Contemporaryphysics[M].S.l.:World Scientific,2008:260.
- [25]WANG Z,WEN P,HUO LS,et al.Signature of viscous flow units in apparent elastic regime of metallic glasses[J].Applied Physics Letters,2012,101(12):869.
- [26]ICHITSUBO T,MATSUBARA E,Yamamoto T,et al.Microstructure of fragile metallic glasses inferred from ultrasoundaccelerated crystallization in pd-based metallic glasses[J].Physical Review Letters,2005,95:245501.
- [27]YU H B,SAMWER K,WANG W H,et al.Chemical influence onβ-relaxations and the formation of molecule-like metallic glasses[J].Nature Communications,2013,4:2204.
- [28]TAKEUCHI,AKIRA,INOUE,AKIHISA.Classification of bulk metallic glasses by atomic size difference,heat of mixing and period of constituent elements and its application to characterization of the main alloying element[J].Materials Transactions,2005,46(12):2817-2829.
- [29]WANG W H.The elastic properties,elastic models and elastic perspectives of metallic glasses[J].Progress in Materials Science,2012,57(3):487-656.
- [30]SHENG H W,MA E,KRAMER M J.Relating dynamic properties to atomic structure in metallic glasses[J].JOM,2012,64(7):856-881.
- [31]PETER W H,LIAW P K,BUCHANAN R A,et al.Fatigue behavior of Zr52.5Al10Ti5Cu17.9Ni14.6bulk metallic glass[J].Intermetallics,2002,10(11-12):1125-1129.
- [32]CHEN M W.Mechanical behavior of metallic glasses:microscopic understanding of strength and ductility[J].Annual Review of Materials Research,2008,38:445-469.
- [33]THOMPSON C F.Progress in metal physics[J].Nature,1960,186:666-666.
- [34]SPAEPEN F.A mcroscopic mechanism for steady state inhomogeneous flow in metallic glasses[J].Acta Metallurgica,1977,25(4):407-415.
- [35]FOGLIA A J.Shear localization and shear instability in materials in the ductile field[J].Journal of structural Geology,1980,2(1-2):135-142.
- [36]LUO P,WEN P,BAI HY,et al.Relaxation decoupling in metallic glasses at low temperatures[J].Physical Review Letters,2017,118(22):225901.
- [37]JOHNSON W L,DEMETRIOU M D,HARMON J S,et al.Rheology and ultrasonic properties of metallic glass-forming liquids:apotential energy landscape perspective[J].MRS Bulletin,2007,32(8):644-650.
- [38]HARMON J S,DEMETRIOU M D,JOHNSON W L,et al.Anelastic to plastic transition in metallic glass-forming liquids[J],Physical Review letters,2007,99(13):135502.
- [39]JOHNSON W L,SAMWER K.A universal criterion for plastic yielding of metallic glasses with a(T/Tg)2/3 temperature dependence[J].Physical Review letters,2005,95:195501.
- [40]RODNEY D,SCHUHC C.Distribution of thermally activated plastic events in a flowing glass[J].Physical Review Letters,2009,102(23):235503.