K(6S)+H_2→KH+H转动分辨反应截面的测量(英文)Rotationally Resolved Cross Sections Measurement for K(6S)+H_2→KH+H Reaction
王倩;吉建强;沈异凡;戴康;
摘要(Abstract):
利用泵浦-检测技术和光学吸收技术,对K(6S)与H2反应生成的初生态产物KH(X1Σ+,v=0,1)的转动态分布和反应截面作了测量。脉冲激光双光子激发K原子至K(6S)态,通过泵浦-探测技术确定了KH(X1Σ+,v=0,1)初生态的转动分布,转动分布接近样品池温时的统计分布。通过测量泵浦激光的能量损失确定K(6S)态原子密度,测量检测激光的吸收系数得到反应产物KH分子的密度,由速率方程分析可以得到转动分辨的反应截面,总的反应截面为所有转动分辨的反应截面之和,得到的反应截面分别为(1.3±0.5)×10-16cm2(对v=0)和(0.05±0.02)×10-16cm2(对v=1).
关键词(KeyWords): 泵浦-检测技术;光学吸收技术;反应截面;K-H2
基金项目(Foundation): Granted by the National Natural Science Foundation of China(10664003)
作者(Authors): 王倩;吉建强;沈异凡;戴康;
参考文献(References):
- [1]Bililign S,Kleiber P D.Nascent rotational quantum state distribution of NaH(NaD)from the reaction of Na(42P)with H 2,D 2,and HD[J].J Chem Phys,1992,96(1):215-217.
- [2]Liu D K,Lin K C.State-specific reaction and product energy disposal of electronically excited potassium with hydrogen molecule[J].J Chem Phys,1997,107(11):4244-4252.
- [3]Fan L H,Chen J J,Lin Y Y,et al.Reaction Rb(5 2 D,7S)of with H 2[J].J Phys Chem A,1999,103:1300-1305.
- [4]Cavero V,LHermite J M.Rahmat G and Vetter R.Cs(6D 3/2)+H 2→CsH+H reaction.IV.Rotationally resolved total cross sections[J].J Chem Phys,1999,110(11):3428-3436.
- [5]Bililign S,Hattablay B C,Geum N,et al.Energy transfer in Li(3P)-H 2 collisions[J].J Phys Chem A,2000,104:9454-9458.
- [6]Wong T H,Kleiber P D,Yang K H.Chemical dynamics of the reaction K(5p 2 P)+H 2→KH(v=0,J)+H:Electronic orbital alignment effects[J].J Chem Phys,1999,110(14):6743-6748.
- [7]Prudente F V,Marques J M C,Maniero A M.Time-dependent wave pachet calculation of the LiH+H reactive scattering on a new potential energy surface[J].Chem Phys Lett,2009,474:18-22.
- [8]Wernli M,Caruso D,Bodo E,et al.Computing three-dimensional electronic energy manifold for the Li(2 P)+H 2 LiH+H chemical reaction[J].J Phys Chem A,2009,113:1121-1128.
- [9]Lin K C,Vetter R.Alkali-hydrogen reaction[J].Int Rev Phys Chem,2002,21(3):357-383.
- [10]Chang Y P,Hsiao M K,Liu D L,et al.Rotational and vibrational state distributions of NaH in the reactions of Na(4 2 S,3 2 D,and6 2 S)with H 2:Insertion harpoon-type mechanisms[J].J Chem Phys,2008,128:234309-1-6.
- [11]Stwalley W C,Zemke W T,Yang S C.Spectroscopy and Structure of the Alkali Hydride Diatomic Molecules and Their ions[J].J Phys Chem Ref Data,1991,20(1),153-186.