武晶斌;刘浪;贾殿赠;郭继玺;盛蕊;

• 1:新疆大学清洁能源材料与技术教育部省部共建重点实验室先进功能材料自治区重点实验室应用化学研究所

摘要(Abstract)：

分别用2,3-二甲基吡嗪,2,5-二甲基吡嗪,四甲基吡嗪做配体,以[Pd(CN)4]2-为构筑基元,与Fe(ClO4)2通过溶液缓慢扩散法制备了三种化合物的单晶.通过分析这三种化合物的晶体结构,发现由于吡嗪上取代基的空间位阻效应,使这些吡嗪衍生物的配位能力比水分子弱,因而形成了水为配体、吡嗪衍生物为客体分子,具有通式为Fe(H2O)2Pd(CN)4.G的二维Hofmann-H2O类配位聚合物.

关键词(KeyWords)： Hofmann类化合物;配位聚合物;吡嗪衍生物;氰基

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(21061014);; 教育部重点项目(209138);; 教育部新世纪优秀人才支持计划(NCET-09-0904);; 新疆大学自然科学基金项目(2009211B02)资助

作者(Author): 武晶斌;刘浪;贾殿赠;郭继玺;盛蕊;

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DOI:

参考文献(References)：

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