1,2:4,5-二-O-异亚丙基-3-C-氰基-β-D-核己-2-酮吡哺糖的相转移催化合成(英文)Study on Phase-Transfer Catalyzed Synthesis of 1, 2: 4, 5-Di-O-Isopropylidene-3-C-Cyano-β-D-Ribo-Hex- 2-ulo Pyranose
于建新,刘育亭
摘要(Abstract)：
1,2:4,5-二-O-异亚丙基-β-D-赤型-2,3-己二酮-2,6-吡喃糖在苯-二氯甲烷和水溶液中与铁(Ⅲ)氰化钾-碳酸钾经相转移催化反应生成氰基支链糖——1,2:4,5-二-O-异亚丙基-3-C-氰基-β-D-核-己-2-酮吡喃糖。产物的构型通过1H和1H和(13)C核磁共振谱及其氢化后的已知化合物——3-氨甲基衍生物得以证实。
关键词(KeyWords)： 氰基支链糖;相转移催化合成
基金项目(Foundation):
作者(Author): 于建新,刘育亭
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